A. B. Vandyshev
THE MAIN STAGES IN THE DEVELOPMENT AND APPLICATION OF MATHEMATICAL SIMULATION FOR THE ANALYSIS OF THE PARAMETERS AND OPERATING CONDITIONS OF MEMBRANE-CATALYTIC DEVICES PRODUCING HIGH PURITY HYDROGEN FROM HYDROCARBON FEEDSTOCK
DOI: 10.17804/2410-9908.2025.3.058-099 The paper discusses the main stages in the development and application of mathematical simulation to analyzing the parameters and operating conditions of promising membrane-catalytic devices designed for the production of high purity hydrogen from hydrocarbon feedstock.
Keywords: membrane-catalytic devices, mathematical simulation, high purity hydrogen, hydrocarbon feedstock References:
- Arutyunov, V.S. Okislitelnaya konversiya prirodnogo gaza [Oxidative Conversion of Natural Gas]. Krasand Publ., Moscow, 2011, 640 p. (In Russian).
- Vandyshev, A.B. and Kulikov, V.A. Energy and resource efficiency in industrial systems for production and use of high-purity hydrogen. Chemical and Petroleum Engineering, 2017, 53, 166–170. DOI: 10.1007/s10556-017-0315-9.
- Klyshnikov, S.T., Kukuy, B.G., Vaisblat, P.M., Maksimov, I.S., and Kotelnikov, A.B. A plant for producing hydrogen from natural gas and water vapor. Stal, 2010, 3, 114–115. (In Russian).
- Pismen, M.K. Proizvodstvo vodoroda v neftepererabatyvayushchey promyshlennosti [Production of Hydrogen in the Oil Refining Industry]. Khimiya Publ., Moscow, 1976, 208 p. (In Russian).
- Oertel, M., Schmitz, J., Weirich, W., Jendryssek-Neumann, D., and Schulten, R. Steam reforming of natural gas with integrated hydrogen separation for hydrogen production. Chemical Engineering Technology, 1987, 10 (1), 248–255. DOI: 10.1002/ceat.270100130.
- Dittmar, B., Behrens, A., Schödel, N., Rüttinger, M., Franco, Th., Straczewski, G., and Dittmeyer, R. Methane steam reforming operation and thermal stability of new porous metal supported tubular palladium composite membranes. International Journal of Hydrogen Energy, 2013, 38 (21), 8759–8771. DOI: 10.1016/j.ijhydene.2013.05.030.
- Tereshchenko, G.F., Orekhova, N.V., and Ermilova, M.M. Metal-containing membrane reactors. Kriticheskie Tekhnologii. Membrany, 2007, 1, 4–20. (In Russian).
- Basile, A., Gallucci, F., and Iulianelli, A. Research activities on hydrogen production using membrane reactors at the ITM-CNR. Kriticheskie Technologii. Membrany, 2007, 2, 3–21. (In Russian).
- Uemiya, S. Brief review of steam reforming using a metal membrane reactor. Topics in Catalysis, 2004, 29 (1), 79–84. DOI: 10.1023/B:TOCA.0000024930.45680.c7.
- Shirasaki, Y., Tsuneki, T., Ota, Y., Yasuda, I., Tachibana, S., Nakajima, H., and Kobayashi, K. Development of membrane reformer system for highly efficient hydrogen production from natural gas. International Journal of Hydrogen Energy, 2009, 34 (10), 4482–4487. DOI: 10.1016/j.ijhydene.2008.08.056.
- Vandyshev, A.B., Makarov, V.M., Muravyev, L.L., Tabachnik, E.B., and Nikishin, S.N. Modeling of high-temperature membrane apparatuses for the production of ultrapure hydrogen. Theoretical Foundations of Chemical Engineering, 1996, 30 (5), 506–508.
- Vandyshev, A.B., Kulikov, V.A., Kirnos, I.V., and Nikishin, S.N. High-temperature membrane apparatuses in systems for repeated utilization of hydrogen. Chemical and Petroleum Engineering, 2006, 42 (11), 640–644. DOI: 10.1007/S10556-006-0155-5.
- Vandyshev, A.B., Kulikov, V.A., and Nikishin, S.N. Analysis of flow-rate characteristics of high-output membrane equipment for the production of ultra-pure hydrogen. Chemical and Petroleum Engineering, 2010, 46, 72–78. DOI: 10.1007/s10556-010-9294-9.
- Вгоегs, G.H.J. and Treijtel, B.W. Carbon deposition boundaries and other constant parameter curves, in the triangular representation of C-H-O equilibria, with applications to fuel cells. Advanced Energy Conversion, 1965, 5 (4), 365–382. DOI: 10.1016/0365-1789(65)90024-X.
- Vandyshev, A.B. About the equilibrium composition monitoring of the technological gaseous mediums in the C-H-0 system under high temperatures. Rasplavy, 2000, 3, 54–63. (In Russian).
- Muravyev, L.L., Vandyshev, A.B., and Makarov, V.M. Modeling of membrane extraction of hydrogen from the products of steam conversion of hydrocarbons. Theoretical Foundations of Chemical Engineering, 1999, 33 (3), 258–263.
- Vandyshev, A.B. Analyzing the parameters of membrane catalytic systems for extraction of highly pure hydrogen from hydrocarbon feedstock with the application of mathematical modeling. Diagnostics, Resource and Mechanics of materials and structures, 2016, 4, 6–45. DOI: 10.17804/2410-9908.2016.4.006-045. Available at: http://dream-journal.org/issues/2016-4/2016-4_87.html
- Vandyshev, A.B. and Kulikov, V.A. Evaluation of efficiency of special-purity hydrogen production from products of steam conversion of methane and its close homologs in high-temperature converter–membrane equipment system using methane or carbon monoxide conversion catalyst. Chemical and Petroleum Engineering, 2013, 48, 566–575. DOI: 10.1007/s10556-013-9659-y.
- Vandyshev, A.B. and Kulikov, V.A. Estimate of high-purity hydrogen production efficiency in membrane-catalytic-systems from reforming products of gasoline, kerosene, and diesel oil. Chemical and Petroleum Engineering, 2017, 53 (9–10), 592–597. DOI: 10.1007/s10556-018-0386-2.
- Lukyanov, B.N. Obtaining ultra-pure hydrogen for fuel cells in the reactors with membrane. Chemistry for Sustainable Development, 2012, 20 (3), 251–263.
- Burkhanov, G.S., Gorina, N.B., Kolchugina, N.B., and Roshan, N.R. Palladium alloys for hydrogen energy. Rossiyskiy Khimicheskiy Zhurnal, 2006, 50 (4), 36–40. (In Russian).
- Sakamoto, Y., Chen, F.L., Furukawa, M., and Noguchi, M. Permeability and diffusivity of hydrogen of in palladium-rich Pd-Y(Gd)-Ag ternary alloys. Journal of Alloys and Compounds, 1992, 185 (2), 191–205. DOI: 10.1016/0925-8388(92)90468-O.
- Vandyshev, A.B. and Kulikov, V.A. Comparison of calculated and experimental flow data for a membrane reformer for special-purity hydrogen production from natural gas. Chemical and Petroleum Engineering, 2014, 49, 660–667. DOI: 10.1007/s10556-014-9815-z.
- Vandyshev, A.B. and Kulikov, V.A. Effect of high-purity hydrogen removal system on performance of membrane-catalytic devices. Chemical and Petroleum Engineering, 2023, 59, 469–476. DOI: 10.1007/s10556-024-01264-2.
- Shigarov, A.B., Кirillov, V.A., Аmosov, Yu.I., Brayko, A.S., Avakov, V.B., Landgraf, I.К., Urusov, A.R., Jivulko, S.A., and Izmaylovich, V.V. Membrane reformer module with Ni-foam catalyst for pure hydrogen production from methane: experimental demonstration and modeling. International Journal of Hydrogen Energy, 2017, 42 (10), 6713–6726. DOI: 10.1016/j.ijhydene.2016.12.057.
- Kirillov, V.A., Shigarov, A.B., Amosov, Yu.I., Belyaev, V.D., and Gerasimov, E.Yu. Production of pure hydrogen from diesel fuel by steam pre-reforming and subsequent conversion in a membrane reactor. Petroleum Chemistry, 2018, 58 (2), 103–113. DOI: 10.1134/S0965544118020020.
- Zhivulko, S.A., Avakov, V.B., Landgraft, I.K., and Urusov, A.R. Experience of practical implementation of hydrocarbon fuel conversion technology with hydrogen extraction from the reaction zone. In: Trudy V Vserossiyskoy konferentsii “Toplivnye elementy i energoustanovki na ikh osnove” [The 5th All-Rissian Conference “Fuel Elements and Power Installation Based on Them”, Suzdal, June 17–21, 2018: Abstracts]. IFTT Publ., Chernogolovka, 2018, pp. 62–64. (In Russian).
- Vandyshev, A.B. and Kulikov, V.A. Analysis of the results of testing an individual disk-type membrane-catalytic module for obtaining high-purity hydrogen from methane. Chemical and Petroleum Engineering, 2019, 55 (9–10), 725–732. DOI: 10.1007/s10556-020-00686-y.
- Vandyshev, A.B. and Kulikov, V.A. Evaluation of design parameters for a 32-module disk-type membrane-catalytic reactor for producing high-purity hydrogen from diesel fuel. Chemical and Petroleum Engineering, 2019, 55 (9–10), 815–820. DOI: 10.1007/s10556-020-00698-8.
- Vandyshev, A.B. A systematic analysis of the parameters of disk-type membrane-catalytic devices for producing high-purity hydrogen from methane and diesel fuel. Diagnostics, Resource and Mechanics of materials and structures, 2020, 4, 6–27. DOI: 10.17804/2410-9908.2020.4.06-27. Available at: http://dream-journal.org/issues/2020-4/2020-4_284.html
- Shirasaki, Y., Sato, T., Itoh, N., Tsuneki, T., Nishii, T., Kurokawa, H., Yasuda, I., Shimamori, T., Takagi, Y., Hikosaka, H., and Tanaka, H. Development of a membrane-on-catalyst hydrogen production module for steam reforming of city gas. Kagaku Kōgaku Ronbunshū, 2017, 43 (5), 336–341. (In Japan). DOI: 10.1252/kakoronbunshu.43.336.
- Vandyshev, A.B. and Kulikov, V.A. Analysis of parameters for producing high-purity hydrogen from natural gas in a tubular type membrane-catalytic module. Chemical and Petroleum Engineering, 2021, 56, 715–720. DOI: 10.1007/s10556-021-00833-z.
- Vandyshev, A.B. and Kulikov, V.A. Assessment of the effects of temperature and pressure on the efficiency of high-purity hydrogen production from hydrocarbon feedstocks in membrane-catalytic devices. Chemical and Petroleum Engineering, 2021, 56, 799–808. DOI: 10.1007/s10556-021-00845-9.
- Shirasaki, Y., Tsuneki, T., Ota, Y., Yasuda, I., Tachibana, S., Nakajima, H., and Kobayashi, K. Development of membrane reformer system for highly efficient hydrogen production from natural gas. International Journal of Hydrogen Energy, 2009, 34 (10), 4482–4487. DOI: 10.1016/j.ijhydene.2008.08.056.
- Goltsov, V.A. Hydrogen in metals. In: Atomno-vodorodnaya energetika i tekhnologiya [Nuclear-Hydrogen Energy and Technology: Collection of Papers]. Atomizdat Publ., Moscow, 1978–1988, 1, pp. 193–230. (In Russian).
- Vandyshev, A.B. Estimating the effect of some individual technological factors on the effectiveness of producing high-purity hydrogen from hydrocarbons in catalytic membrane devices. Diagnostics, Resource and Mechanics of materials and structures, 2022, 4, 6–36. DOI: 10.17804/2410-9908.2022.4.006-036. Available at: http://dream-journal.org/issues/2022-4/2022-4_359.html
- Vandyshev, A.B. Estimating the effect of the main design parameters on the effectiveness of high-purity hydrogen production from raw hydrocarbons in membrane catalytic devices. Diagnostics, Resource and Mechanics of materials and structures, 2023, 4, 29–46. DOI: 10.17804/2410-9908.2023.4.029-046. Available at: http://dream-journal.org/issues/2023-4/2023-4_405.html
- Baboshin, V.M., Buevich, Yu.A., Ivonin, A.K., Kirnos, I.V., and Kukui, B.G. Diffusion separation of hydrogen from gas mixtures. Journal of Engineering Physics, 1984, 47 (1), 821–826. DOI: 10.1007/BF00832599.
- Vandyshev, A.B. Recommendations on optimizing a number of process and design parameters of membrane catalytic devices for producing high-purity hydrogen from crude hydrocarbons. Diagnostics, Resource and Mechanics of materials and structures, 2024, 5, 46–68. DOI: 10.17804/2410-9908.2024.5.046-068. Available at: http://dream-journal.org/issues/2024-5/2024-5_462.html
Article reference
Vandyshev A. B. The Main Stages in the Development and Application of Mathematical Simulation for the Analysis of the Parameters and Operating Conditions of Membrane-Catalytic Devices Producing High Purity Hydrogen from Hydrocarbon Feedstock // Diagnostics, Resource and Mechanics of materials and structures. -
2025. - Iss. 3. - P. 58-99. - DOI: 10.17804/2410-9908.2025.3.058-099. -
URL: http://eng.dream-journal.org/issues/content/article_520.html (accessed: 04/22/2026).
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