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V. V. Portnyagina, N. N. Petrova, N. P. Ovchinnikov, A. N. Martynova

STUDYING THE STRUCTURE AND PROPERTIES OF ELASTOMERIC COMPOSITES DESIGNED TO OPERATE UNDER EXTREME CONDITIONS

DOI: 10.17804/2410-9908.2017.2.034-039

The paper presents results of studying the main operational properties and structure of sealing rubbers based on propylene oxide rubber and ultrafine polytetrafluoroethylene intended for extreme operating conditions. It is shown that, to achieve a positive effect on the material properties, it will suffice to add to the rubber compound 0.5–1 wt % of polymer per 100 wt % of rubber. This is due to the high activity of UPTFE particles, their nanostructured arrangement and better uniformity of their distribution in the volume of the elastomeric matrix. RF and US patents for rubber formulations have been taken out.

Keywords: sealing materials, propylene oxide rubber, ultrafine polytetrafluoroethylene, frost resistance, wear resistance, structure of elastomeric material, electron microscopy

References:

  1. Okhlopkova A.A., Adrianova O.A., Popov S.N. Modifikatsiya polimerov ultradispersnymi soedineniyami [Modification of Polymers by Ultradispersed Compounds]. Yakutsk, Izd-vo SO RAN Publ., 2003, 224 p. (In Russian).
  2. Selyutin G.E., Gavrilov Yu.Yu., Voskresenskaya E.N., Zakharov V.A., Nikitin V.Е., Poluboyarov V.А. Composite materials based on ultra-high molecular weight polyethylene: properties, prospects of use. Chemistry for Sustainable Development, 2010, vol. 18, no. 3, pp. 375–388. (In Russian).
  3. Okhlopkova A.A., Petrova P.N., Gogoleva O.V. Wear-resistant composite materials based on ultra-high molecular weight polyethylene meant for operation under extreme conditions. Materialovedenie, 2011, no. 9, pp. 10–13. (In Russian).
  4. Andreeva I.N., Veselovskaya Е.V., Nalivaiko E.I. Sverkhmolekulyarnyi polietilen vysokoy plotnosti [Ultra-High Molecular Weight Polyethylene]. L., Khimiya Publ., 1982, 80 p. (In Russian).
  5. Junges Fernando, Beauvalet Mariana, Leal Bárbara C., Casagrande Adriana C. A., Mota Fábio F., Mauler Raquel S., Casagrande Jr. Osvaldo L. UHMWPE-Layered Silicate Nanocomposites by in situ Polymerization with Tris(pyrazolyl)borate Titanium/Clay Catalyst. J. Braz. Chem. Soc., 2009, vol. 20, no. 3, pp. 472–477. DOI: 10.1590/S0103-50532009000300010.
  6. Brevnov P.N. Polyethylene- and montmorillonite-based nanocomposite materials: synthesis, structure, properties. Ph.D thesis, 2008. (In Russian).
  7. Sleptsova S.A., Afanasieva E.S., Grigorieva V.P. Structure and tribological behavior of polytetrafluoroethylene modified with layered silicates. Journal of Friction and Wear, 2009, vol. 30, no. 6, pp. 1–7. DOI: 10.3103/S1068366609060105.
  8. Myshkin N.K., Petrokovets M.I. Trenie, smazka, iznos. Fizicheskie osnovy i tekhnicheskie prilozheniya tribologii [Friction, Lubrication, Wear. Basic Physics and Engineering Applications of Tribology]. M., Fizmatlit Publ., 2007, 368 p. (In Russian).
  9. Mashkov Yu.K., Ovchar Z.N., Surikov V.I., Kalistratova L.F. Kompozitsionnye materialy na osnove politetraftoretilena. Strukturnaya modifikatsiya [Polytetrafluoroethylene-Based Composite Materials. Structural Modification]. Moscow, Mashinostroenie Publ., 2005, 240 p. (In Russian).


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Article reference

Studying the Structure and Properties of Elastomeric Composites Designed to Operate under Extreme Conditions / V. V. Portnyagina, N. N. Petrova, N. P. Ovchinnikov, A. N. Martynova // Diagnostics, Resource and Mechanics of materials and structures. - 2017. - Iss. 2. - P. 34-39. -
DOI: 10.17804/2410-9908.2017.2.034-039. -
URL: http://eng.dream-journal.org/issues/content/article_125.html
(accessed: 11/21/2024).

 

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