R. A. Savrai , P. A. Skorynina, A. V. Makarov , L. Kh. Kogan, M. B. Rigmant, A. I. Men’shakov
THE EFFECT OF FRICTION PROCESSING AND LOW-TEMPERATURE PLASMA CARBURIZING ON THE MAGNETIC PROPERTIES OF THE AISI 321 AUSTENITIC STAINLESS STEEL
DOI: 10.17804/2410-9908.2025.6.006-022 The paper investigates the magnetic properties of the AISI 321 corrosion-resistant austenitic steel subjected to electron beam plasma carburizing at temperatures of 350 and 500 °C, friction processing with a sliding indenter, and different kinds of combined processing including friction processing and plasma carburizing. It is found that plasma carburizing, friction processing, and combined processing of the AISI 321 steel are accompanied by a change in the magnetic parameters of the modified surface layers, which, in turn, is due to a change in the structural and phase state. Moreover, the AISI 321 steel exhibits the highest values of relative magnetic permeability μr and coercive force Hc after combined processing including friction processing and plasma carburizing at T = 350 °C, which ensures maximum surface hardness and the maximum possible depth of the modified surface layer. The obtained results indicate a high sensitivity of magnetic properties to changes in the structural and phase state of thin surface layers of the AISI 321 austenitic steel, and they can be used to develop magnetic techniques for testing the quality of surface hardening treatments (including combined ones) of austenitic chromium-nickel steels.
Acknowledgment: This study was performed under the state assignments for the IES UB RAS, reg. No. 124020600045-0, the IMP UB RAS, Nos. 122021000033-2 (Structure) and 122021000030-1 (Diagnostics), and the IEP UB RAS, No. 125020601664-1. The equipment of the Plastometriya shared research facilities at the IES UB RAS was used for the structural studies. Keywords: corrosion-resistant austenitic steel, plasma carburizing, friction processing, magnetic properties References:
- Tsujikawa, M., Egawa, M., Sone, T., Ueda, N., Okano, T., and Higashi, K. Modification of S phase on austenitic stainless steel using fine particle shot peening. Surface and Coatings Technology, 2013, 228 (suppl. 1), S318–S322. DOI: 10.1016/j.surfcoat.2012.05.111.
- Shabashov, V.A., Korshunov, L.G., Litvinov, A.V., Kataeva, N.V., and Zamatovsky, A.E. Increasing the depth of the nitrided layer in the surface of austenitic alloys using friction treatment. Diagnostics, Resource and Mechanics of materials and structures, 2016, 6, 17–27. DOI: 10.17804/2410-9908.2016.6.017-027. Available at: http://dream-journal.org/issues/ 2016-6/2016-6_108.html
- Menezes, M.R., Godoy, C., Buono, V.T.L., Schvartzman, M., and Avelar-Batista Wilson, J.C. Effect of shot peening and treatment temperature on wear and corrosion resistance of sequentially plasma treated AISI 316L steel. Surface and Coatings Technology, 2017, 309, 651–662. DOI: 10.1016/j.surfcoat.2016.12.037.
- Makarov, A.V., Gavrilov, N.V., Samoylova, G.V., Mamaev, A.S., Osintseva, A.L., and Savrai, R.A. Effect of a continuous and gas-cyclic plasma nitriding on the quality of nanostructured austenitic stainless steel. Obrabotka Metallov (Tekhnologiya, Oborudovanie, Instrumenty), 2017, 75 (2), 55–66. (In Russian). DOI: 10.17212/1994-6309-2017-2-55-66.
- Makarov, A.V., Samoilova, G.V., Gavrilov, N.V., Mamaev, A.S., Osintseva, A.L., and Savrai, R.A. The influence of preliminary deformation treatment on the hardening and quality of the nitrided surface of austenite stainless steel. Vektor Nauki Tolyattinskogo Gosudarstvennogo Universiteta, 2017, 42 (4), 67–74. (In Russian). DOI: 10.18323/2073-5073-2017-4-67-74.
- Lin, Y., Lu, J., Wang, L., Xu, T., and Xue, Q. Surface nanocrystallization by surface mechanical attrition treatment and its effect on structure and properties of plasma nitride AISI 321 stainless steel. Acta Materialia, 2006, 54, 5599–5605. DOI: 10.1016/j.actamat.2006.08.014.
- Jayalakshmi, M., Huilgol, P., Bhat, B.R., and Bhat, K.U. Microstructural characterization of low temperature plasma-nitrided 316L stainless steel surface with prior severe shot peening. Materials and Design, 2016, 108, 448–454. DOI: 10.1016/j.matdes.2016.07.005.
- Liu, Zh., Peng, Y., Chen, Ch., Gong, J., and Jiang, Y. Effect of surface nanocrystallization on low-temperature gas carburization for AISI 316L austenitic stainless steel. International Journal of Pressure Vessels and Piping, 2020, 182, 104053. DOI: 10.1016/j.ijpvp.2020.104053.
- Zhidkov, I.S., Kukharenko, A.I., Makarov, A.V., Savrai, R.A., Gavrilov, N.V., Cholakh, S.O., and Kurmaev, E.Z. XPS characterization of surface layers of stainless steel nitrided in electron beam plasma at low temperature. Surface and Coatings Technology, 2020, 386, 125492. DOI: 10.1016/j.surfcoat.2020.125492.
- Lu, Y., Li, D., Ma, H., Liu, X., Wu, M. and Hu, J. Enhanced plasma nitriding efficiency and properties by severe plastic deformation pretreatment for 316L austenitic stainless steel. Journal of Materials Research and Technology, 2021, 15, 1742–1746. DOI: 10.1016/j.jmrt.2021.08.082.
- Unal, O., Maleki, E., and Varol, R. Plasma nitriding of gradient structured AISI 304 at low temperture: shot peening as a catalyst treatment. Vacuum, 2019, 164, 194–197. DOI: 10.1016/j.vacuum.2019.03.027.
- Savrai, R.A., Skorynina, P.A., Makarov, A.V., Menshakov, A.I., and Gaviko, V.S. The influence of frictional treatment and low-temperature plasma carburizing on the structure and phase composition of metastable austenitic steel. Physics of Metals and Metallography, 2023, 124 (5), 496–503. DOI: 10.1134/S0031918X23600483.
- Savrai, R.A., Skorynina, P.A., Makarov, A.V., Kogan, L.Kh., and Menshakov, A.I. The influence of frictional treatment and low-temperature plasma carburizing on the microhardness and electromagnetic properties of metastable austenitic steel. Physics of Metals and Metallography, 2023, 124 (8), 816–823. DOI: 10.1134/S0031918X23601166.
- Skorynina, P.A., Makarov, A.V., Menshakov, A.I., and Osintseva, A.L. Effect of low-temperature carburization in electron beam plasma on the hardening and surface roughness of the metastable austenitic steel. Obrabotka Metallov (Tekhnologiya, Oborudovanie, Instrumenty), 2019, 21 (2), 97–109. (In Russian). DOI: 10.17212/1994-6309-2019-21.2-97-109.
- Nichipuruk, A.P., Stashkov, A.N., Kostin, V.N., Murikov, S.A., and Murikov, E.S. Coercimetric quality testing of steel parts. Ural school of coercimetry. V Mire NK, 2015, 18 (4), 9–13. (In Russian). DOI: 10.12737/14951.
- Mikheev, M.N. and Gorkunov, E.S. Magnitnye metody strukturnogo analiza i nerazrushayushchego kontrolya [Magnetic Methods of Structural Analysis and Nondestructive Testing]. Nauka Publ., Moscow, 1993, 249 p. (In Russian).
- Rigmant, M.B., Kazantseva, N.V., Kochnev, A.V., Koemets, Yu.N., Korkh, Yu.V., Korkh, M.K., and Karabanalov, M.S. Revealing magnetic anisotropy in austenitic chromium–nickel steel after rolling. Russian Journal of Nondestructive Testing, 2021, 57 (12), 1113–1119. DOI: 10.1134/S1061830921120081.
- Rigmant, M.B. and Korkh, M.K. Control of the phase composition and magnetic properties of products made of austenitic-ferritic and austenitic-martensitic steels. Vestnik Kontserna VKO “Almaz–Antey”, 2020, 3, 45–53. (In Russian). DOI: 10.38013/2542-0542-2020-3-45-53.
- Lunev, A.G. and Nadezhkin, M.V. Heat criterion of the change of strain-hardening stages in austenitic stainless steel. The Physics of Metals and Metallography, 2019, 120 (10), 1021–1025. DOI 10.1134/S0031918X19080118.
- Ye, D. Investigation of cyclic deformation behavior in the surface layer of 18Cr–8Ni austenitic stainless steel based on Vickers microhardness measurement. Materials Chemistry and Physics, 2005, 93, 495–503. DOI: 10.1016/j.matchemphys.2005.03.031.
- Peng, Y., Gong, J., Jiang, Y., Fu, M., and Rong, D. The effect of plastic pre-strain on low-temperature surface carburization of AISI 304 austenitic stainless steel. Surface and Coatings Technology, 2016, 304, 16–21. DOI: 10.1016/j.surfcoat.2016.05.047.
- Astafurova, E.G., Melnikov, E.V., and Astafurov, S.V. Hydrogen-enhanced martensitic transformation and twinning under rolling of AISI 321 austenitic stainless steel. Reviews on Advanced Materials and Technologies, 2024, 6 (3), 120–131. DOI: 10.17586/2687-0568-2024-6-3-120-131.
- Klevtsov, G.V., Valiev, R.Z., Klevtsova, N.A., Enikeev, N.A., Pigaleva, I.N., Abramova, M.M., and Frolova, O.A. Effect of severe plastic deformation on martensitic transformations in a metastable austenitic steel. Letters on Materials, 2023, 13 (4s), 397–402. DOI: 10.22226/2410-3535-2023-4-397-402.
- Liu, H.Y., Che, H.L., Gao, J.Y., Li, G.B., and Lei, M.K. Low-pressure hollow cathode plasma source carburizing of AISI 304L austenitic stainless steel at low temperature. Surface and Coatings Technology, 2022, 442, 128548. DOI: 10.1016/j.surfcoat.2022.128548.
- Kaciulis, S., Lanzutti, A., Mezzi, A., Montanari, R., Palombi, A., Picco, N., Vaglio, E., Varone, A., and Verona, C. Low temperature plasma carburizing of additive manufactured 316L steel: the effect of treatment time on tribological behavior. Journal of Materials Research and Technology, 2025, 36, 9962–9977. DOI: 10.1016/j.jmrt.2025.05.219.
- Ciancaglioni, I., Donnini, R., Kaciulis, S., Mezzi, A., Montanari, R., Ucciardello, N. and Verona-Rinati, G. Surface modification of austenitic steels by low temperature carburization. Surface and Interface Analysis, 2012, 44 (8), 1001–1004. DOI: 10.1002/sia.4894.
- Tong, X., Zhang, T., and Ye, W. Effect of carburizing atmosphere proportion on low temperature plasma carburizing of austenitic stainless steel. Advanced Materials, Mechanics and Industrial Engineering, 2014, 598, 90–93. DOI: 10.4028/www.scientific.net/AMM.598.90.
- Gobbi, S.J., Gobbi, V.J., and Reinke, G. Improvement of mechanical properties and corrosion resistance of 316L and 304 stainless steel by low temperature plasma cementation. Matéria (Rio de Janeiro), 2020, 25 (2), e-12636. DOI: 10.1590/S1517-707620200002.1036.
- Putilova, E.A., Goruleva, L.S., and Zadvorkin, S.M. Effect of frictional treatment of the AISI 321 steel on the change of its hardness and magnetic characteristics. Diagnostics, Resource and Mechanics of materials and structures, 2022, 5, 40–49. (In Russian). DOI: 10.17804/2410-9908.2022.5.040-049. Available at: http://dream-journal.org/issues/2022-5/2022-5_364.html
- Austenitic Chromium-Nickel Stainless Steels at Ambient Temperatures – Mechanical and Physical Properties: A Practical Guide to the Use of Nickel-Containing Alloys No 2978, Nickel Institute, 2021, 43 p.
- Sinha, P., Chakravarty, S., Singh, R., Singh, P.K., and Murthy, G.V.S. Magnetization study of the sensitization in SS304LN. Materials Research Bulletin, 2019, 109, 149–154. DOI: 10.1016/j.materresbull.2018.09.028.
- Silva, I.C., Rebello, J.M.A., Bruno, A.C., Jacques, P.J., Nysten, B., and Dille, J. Structural and magnetic characterization of a carburized cast austenitic steel. Scripta Materialia, 2008, 59 (9), 1010–1013. DOI: 10.1016/j.scriptamat.2008.07.015.
- Schuler, P., Krupp, U., Gümpel, P., Mayer, J., Schwedt, A., and Aretz, A. Investigation of alloy-dependent occurrence of ferromagnetism in carbon-expanded austenitic steel after low-temperature surface hardening. Steel Research International, 2021, 92 (12), 2100272. DOI: 10.1002/srin.202100272.
- Borgioli, F. Low‐temperature thermochemical treatments of face‐centered cubic alloys: new perspectives for expanded austenite from austenitic stainless steels to high‐entropy alloys. MetalMat, 2025, 2 (3), e70013. DOI: 10.1002/metm.70013.
- Barba-Juan, A., Vicente, N., Mormeneo-Segarra, A., and Clausell-Terol, C. Microstructure-dependent magnetic permeability in ferrites from nanoparticles. Ceramics International, 2023, 49 (13), 21530–21537. DOI: 10.1016/j.ceramint.2023.03.287.
- Polyakov, V.V. and Egorov, A.V. Dependence of the magnetic permeability of ferromagnetic powder materials on particle size. Powder Metallurgy and Metal Ceramics, 1995, 33 (1–2), 9–10. DOI: 10.1007/BF00559698.
- Gorkunov, E.S. Magnetic structural-phase analysis as applied to diagnosing and evaluating the lifetime of products and structural components. Part 1. Diagnostics, Resource and Mechanics of materials and structures, 2015, 1, 6–40. DOI: 10.17804/2410-9908.2015.1.006-040. Available at: http://dream-journal.org/issues/2015-1/2015-1_19.html
- Korkh, M.K., Rigmant, M.B., Sazhina, E.Yu., and Kochnev, A.V. Measuring ferromagnetic phase content based on magnetic properties in two-phase chromium–nickel steels. Russian Journal of Nondestructive Testing, 2019, 55 (11), 837–850. DOI: 10.1134/S1061830919110056.
- Makarov, A.V., Savrai, R.A., Gorkunov, E.S., Malygina, I.Yu., Kogan, L.K., Pozdejeva, N.A. and Kolobylin, Yu.M. Effect of friction-induced hardening on the features of magnetic and eddy-current behavior of an annealed structural steel under cyclic loading conditions. Russian Journal of Nondestructive Testing, 2008, 44 (7), 496–508. DOI: 10.1134/S1061830908070085.
- Jiles, D.C. The effect of compressive plastic deformation on the magnetic properties of AISI 4130 steels with various microstructures. Journal of Physics D: Applied Physics, 1988, 21 (7), 1196–1204. DOI: 10.1088/0022-3727/21/7/023.
Article reference
The Effect of Friction Processing and Low-Temperature Plasma Carburizing on the Magnetic Properties of the Aisi 321 Austenitic Stainless Steel / R. A. Savrai, P. A. Skorynina, A. V. Makarov, L. Kh. Kogan, M. B. Rigmant, A. I. Men’shakov // Diagnostics, Resource and Mechanics of materials and structures. -
2025. - Iss. 6. - P. 6-22. - DOI: 10.17804/2410-9908.2025.6.006-022. -
URL: http://eng.dream-journal.org/issues/2025-6/2025-6_526.html (accessed: 04/18/2026).
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