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V. B. Vykhodets, T. E. Kurennykh

DIFFUSION OF DEUTERIUM IN THE InSb SEMICONDUCTOR AT LIQUID NITROGEN TEMPERATURE

DOI: 10.17804/2410-9908.2025.5.029-038

The online nuclear reaction technique is used to measure the deuterium diffusion coefficient in the InSb semiconductor at liquid nitrogen temperatures. It has been found that diffusion follows the classical mechanism of over-barrier atomic jumps. Diffusion activation energy is evaluated to be very low, approximately 0.1 eV; this correlates with the low atomic packing factor of the InSb crystal lattice, which is approximately 34%. These are the first experimental data on hydrogen diffusion in a semiconductor at cryogenic temperature and in a solid with an extremely low atomic packing factor.

Acknowledgment: The work was performed under the state assignment of the Russian Ministry of Science and Higher Education for the IMP UB RAS. We express our gratitude to Dr. O. A. Nefedova for her as-sistance.

Keywords: hydrogen, semiconductor, InSb, tunneling, equilibrium positions, Debye temperature, quantum diffusion, experimental techniques

References:

  1. Völkl, J. and Alefeld, G. Diffusion of hydrogen in metals. In: Alefeld, G., Völkl, J., eds. Hydrogen in Metals I. Topics in Applied Physics, Springer, Berlin, Heidelberg, 1978, vol 28, pp. 321−348. DOI: 10.1007/3540087052_51.
  2. Bakker, H., Bonzel, H.P. Bruff, C.M. et al. Diffusion in Solid Metals and Alloys, Mehrer, H., ed., Springer, Berlin, Heidelberg, 1990, vol. 26, 747 p.
  3. Kimizuka, H., Ogata, S., and Shiga, M. Unraveling anomalous isotope effect on hydrogen diffusivities in fcc metals from first principles including nuclear quantum effects. Physical Review B, 2019, 100 (2), 024104. DOI: 10.1103/PhysRevB.100.024104.
  4. Kashlev, Yu.A. Three regimes of diffusion migration of hydrogen atoms in metals. Theoretical and Mathematical Physics, 2005, 145, 1590−1603. DOI: 10.1007/s11232-005-0185-8.
  5. Fang, W., Richardson, J.O., Chen, J., Li, X.Z., and Michaelides, A. Simultaneous deep tunneling and classical hopping for hydrogen diffusion on metals. Phys Rev Lett., 2017, 119 (12), 126001. DOI: 10.1103/PhysRevLett.119.126001.
  6. Sundell, P.G. and Wahnström, G. Activation energies for quantum diffusion of hydrogen in metals and on metal surfaces using delocalized nuclei within the density-functional theory. Phys Rev Lett., 2004, 92 (15), 155901. DOI: 10.1103/PhysRevLett.92.155901.
  7. Di Stefano, D., Mrovec, M., and Elsässer, C. First-principles investigation of quantum mechanical effects on the diffusion of hydrogen in iron and nickel. Phys. Rev. B, 2015, 92 (22), 224301. DOI: 10.1103/PhysRevB.92.224301.
  8. Vykhodets, V., Nefedova, O., Kurennykh, T., and Vykhodets, E. First observation of quantum diffusion in non-cubic metal: deuterium diffusion in In. Metals, 2023, 13, 394. DOI: 10.3390/met13020394.
  9. Vykhodets, V.B., Kurennykh, T.E., Nefedova, O.A., Gorelov, V.P., Stroeva, A.Yu., Balakireva, V.B., Vykhodets, E.V., and Obukhov, S.I. Deuterium diffusion in proton conductors La0.9Sr0.1ScO3‑δ and BaZr0.9Y0.1O3‑δ at room temperature. Solid State Ionics, 2014, 263, 152–156. DOI: 10.1016/j.ssi.2014.06.003.
  10. Ziegler, J.F., Biersack, J.P., and Ziegler, M.D. SRIM – The Stopping and Ranges of Ions in Matter. Available at: http://www.srim.org (accessed April 10, 2019).
  11. Crank, J. The Mathematics of Diffusion, 2nd ed., Oxford University Press, 1975, 414 p.
  12. Schober, H.R. and Stoneham, A.M. Diffusion of hydrogen in transition metals. Journal of the Less Common Metals, 1991, 172–174, 538–547. DOI: 10.1016/0022-5088(91)90174-3.
  13. Johnson, D.F. and Carter, E.A. Hydrogen in tungsten: absorption, diffusion, vacancy trapping, and decohesion. J. Mater. Res., 2010, 25, 315–327. DOI: 10.1557/jmr.2010.0036.
  14. Jiang, D.E. and Carter, E.A. Diffusion of interstitial hydrogen into and through bcc Fe from first principles. Physical Review B, 2004, 70, 064102. DOI: 10.1103/PhysRevB.70.064102.
  15. Yoshikawa, T., Takayanagi, T., Kimizuka, H., and Shiga, M. Quantum-thermal crossover of hydrogen and tritium diffusion in α-iron. J. Phys. Chem. C, 2012, 116, 23113–23119. DOI: 10.1021/jp307660e.
  16. Kimizuka, H., Mori, H., and Ogata, S. Effect of temperature on fast hydrogen diffusion in iron: a path-integral quantum dynamics approach. Phys. Rev. B, 2011, 83, 094110. DOI: 10.1103/PhysRevB.83.094110.
  17. Pearton, S.J., Corbett, J.W., and Borenstein, J.T. Hydrogen diffusion in crystalline semiconductors. Physica B: Condensed Matter, 1991, 170 (1–4), 85–97. DOI: 10.1016/0921-4526(91)90109-R.
  18. Trotta, R., Giubertoni, D., Polimeni, A., Bersani, M., Capizzi, M., Martelli, F., Rubini, S., Bisognin, G., and Berti, M. Hydrogen diffusion in GaAs1−


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    Article reference

    Vykhodets V. B., Kurennykh T. E. Diffusion of Deuterium in the Insb Semiconductor at Liquid Nitrogen Temperature // Diagnostics, Resource and Mechanics of materials and structures. - 2025. - Iss. 5. - P. 29-38. -
    DOI: 10.17804/2410-9908.2025.5.029-038. -
    URL: http://eng.dream-journal.org/issues/2025-5/2025-5_530.html
    (accessed: 04/22/2026).

     

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