Electronic Scientific Journal
 
Diagnostics, Resource and Mechanics 
         of materials and structures
Рус/Eng  

 

advanced search

IssuesAbout the JournalAuthorContactsNewsRegistration

2015 Issue 1

All Issues
 
2024 Issue 2
 
2024 Issue 1
 
2023 Issue 6
 
2023 Issue 5
 
2023 Issue 4
 
2023 Issue 3
 
2023 Issue 2
 
2023 Issue 1
 
2022 Issue 6
 
2022 Issue 5
 
2022 Issue 4
 
2022 Issue 3
 
2022 Issue 2
 
2022 Issue 1
 
2021 Issue 6
 
2021 Issue 5
 
2021 Issue 4
 
2021 Issue 3
 
2021 Issue 2
 
2021 Issue 1
 
2020 Issue 6
 
2020 Issue 5
 
2020 Issue 4
 
2020 Issue 3
 
2020 Issue 2
 
2020 Issue 1
 
2019 Issue 6
 
2019 Issue 5
 
2019 Issue 4
 
2019 Issue 3
 
2019 Issue 2
 
2019 Issue 1
 
2018 Issue 6
 
2018 Issue 5
 
2018 Issue 4
 
2018 Issue 3
 
2018 Issue 2
 
2018 Issue 1
 
2017 Issue 6
 
2017 Issue 5
 
2017 Issue 4
 
2017 Issue 3
 
2017 Issue 2
 
2017 Issue 1
 
2016 Issue 6
 
2016 Issue 5
 
2016 Issue 4
 
2016 Issue 3
 
2016 Issue 2
 
2016 Issue 1
 
2015 Issue 6
 
2015 Issue 5
 
2015 Issue 4
 
2015 Issue 3
 
2015 Issue 2
 
2015 Issue 1

 

 

 

 

 

L. F. Koroleva

NANOPARTICULATE ZIRCONIA-MODIFIED SOLID SOLUTIONS OF ALUMINUM-IRON OXIDES FOR POLISHING TITANIUM METAL

DOI: 10.17804/2410-9908.2015.1.090-102

A synthesis mechanism of nanoparticulate zirconia-modified Al2–xFexO3 solid solutions has been studied with the application of X-ray diffraction, IR spectroscopy, DTA, particle-size analysis and chemical analysis. The solid solutions have been prepared via heat treatment of ammonium hydroxycarbonate complexes. The nanoparticles are shown to consist of crystalline rhombohedral α-Al2–xFexO3, monoclinic and tetragonal (M-ZrO2 and T-ZrO2). The synthesized mixed oxide offers a high polishing ability (3 to 4.5 times as high), as demonstrated in polishing of titanium, and ensures surface roughness values Ra ranging between 0.019 and 0.009 μm.

Keywords: aluminum-iron oxides, zirconia, X-Ray diffraction, polishing, titanium, nano-roughened surface.

References:

1. Jackson M.J., Mills B., Hitchiner. M.P. Controlled Wear of Vitrified Abrasive Materials for Precision Grinding Applications. Sadhana, 2003, vol. 28, pp. 897–914.
2. Givi M., Tehrani A.F., Mohammadi A. Polishing of the aluminum sheets with magnetic abrasive finishing method.m Int. J. Adv. Manuf. Technol., 2012, vol. 61, pp. 989–998. ISSN 0268-3768.
3. Artemov A.S. Polishing Nanodiamonds. Physics of the Solid State, 2004, vol. 46, pp. 687–695. ISSN: 1063-7834.
4. Bakharev V.P. Dispersion of Ceramics and Composites in Diamond Finishing by Free Abrasive. Russian Engineering Research, 2009, vol. 29, pp. 162–168. ISSN 1068-798X.
5. Filatova Yu.D., Yashchuk V.P., Filatov A.Yu., Heisel U., Storchak M., Monteil G. Assessment of Surface Roughness and Reflectance of Nonmetallic. Products upon Diamond Abrasive Finishing. Journal of Superhard Materials, 2009, vol. 31, no. 5, pp. 338–346. ISSN: 1063-4576.
6. Storozhenko P.A., Guseinov Sh.L., Malashin S.I. Nanodispersed Powders: Synthesis, Methods and Practical Applications. Nanotechnol. Russia, 2009, vol. 4, pp. 262–274. ISSN 1995-0780.
7. Pokropivnyi V.V., Silenko P.M. Silicon Carbide Nanotubes and Nanotubular Fibers: Synthesis, Stability, Structure and Classification. Theor. Exp. Chem., 2006, vol. 42, pp. 3–15. DOI 0040-5760/06/4201-0003.
8. Khanra A.K. Production of Boron Carbide Powder by Carbothermal Synthesis of Gel Material. Bull. Mater. Sci., 2007, vol. 30, pp. 93–96.
9. Bogdanov S.P. Influence of Superstoichiometric Boron on the Synthesis of Cubic Boron Nitride. Glass Phys. Chem., 2008, vol. 34, pp. 336–339. ISSN 1087-6596.
10. Song X.-l., Qu P., Yang H.-P., He X., Qiu G.- Z. Synthesis of γ-Al2O3 Nanoparticles by Chemical Precipitation Method. J. Cent. South Univ. Technol., 2005, vol. 12, pp. 536–541.DOI: 10.1007/s11771-005-0118-6. 
11. Garshin A.P., Gropyanov V.M., Lagunov Yu.V. Abrazivnye materialy [Abrasive Materials]. Leningrad, Mashinostroenie Publ., 1983, 230 p. (In Russian).
12. Viktorov V.V., Fotiev A.A., Badich V.D. Abrasive and Thermal Properties of Al2O3-Cr2O3 Solid Solutions. Inorg. Mater., 1996, vol. 32, no 55, pp. 55–57 ISSN 0020-1685.
13. Chekhomova L.F. Abrasive Properties of Modified Chromia. Inorg. Mater., 2001, vol. 37, p. 274. ISSN 0020-1685.
14. Koroleva L.F. Modifitsyrovannye oksidy, oksogidroksid, shpineli khroma, dlya abrazivnykh i pigmentnykh materialov [Modified Oxides, Oxyhydroxide, Chromium Spinels for Abrasive and Pigmentary Materials]. Ekaterinburg, UrO RAN Publ., 2002, 217 p. ISBN 5-7691-1236-0.
15. Rogov V.V., Rublev N.D., Krotenko T.L., Troyan A.V. A Study of Intensity of Tribochemical Contact Interaction between a Polishing Compound and Sapphire in Machining. Sverkhtverd. Mater., 2008, no. 4, pp. 75–78. (In Russian).
16. Koroleva L.F.. Abrasive Properties of Aluminum Iron Oxide Nanoparticles. Inorg. Mater., 2009, vol. 45, p. 1158. ISSN 0020-1685.
17. Koroleva L.F. Synthesis and Abrasive Properties of Nanoparticulate MoO2-Modified Al2 –xFexO3 and Fe2 –yAlyO3 Solid Solutions. Inorg. Mater., 2010, vol. 46, p. 1330. ISSN 0020-1685.
18. Dogadkina E.V., Dontsov M.G., Parfenyuk V.I. Chem. Polishing of titanium. Izv.Vuzov, Ser. Khimiya. Khim. Tekhnol., 2011, vol. 54, no 3, pp. 65–68. (In Russian).
19. Kim J., Lim E., Jung Y. Determination of efficient superfinishing conditions for mirror surface finishing of titanium. J. Cent. South Univ., 2012, vol. 19, pp. 155−162. ISSN: 2095-2899.
20. Koroleva L.F. Final Polishing of Metals to Obtain Nanoroughened Surface with nanoparticulate complex oxides of aluminum and iron. Chapter 6. In Book: Recent Advances in Abrasives Research, P. 286, Ed. Prof. Dirk Bähre. Nova Science Publishers. 2013, pp.173–211. ISBN: 978-1-62808-566-2.
21. Andryushchenko L.A., Grinev B.V., Tarasov V.A. Influence of the Surface State of Inorganic Scintillation Materials on Their Performance Characteristics (Review). Instruments and Experimental Techniques, 2011, vol. 54, no. 5, pp. 603–631. ISSN 0020-4412.
22. Safronov A.P., Kalinina E.G., Blagodetelev D.A., Kotov Yu.A. Separation of Aluminum Oxide Powders with Different Degrees of Aggregation by Sedimentation in an Aqueous Medium. Nanotechnol. Russia, 2010, vol. 5, p. 498. ISSN 1995-0780.
23. Belousov V.M., Chertov V.M., Rozhkova E.V., Litvin V.I., Zazhigalov V.A. A Sol-Gel Method for Synthesizing Porous Iron-Aluminum Oxide Substances and Regulation of their Physicochemical Characteristics. Theoretical and Experimental Chemistry, 1997, vol. 33, pp. 120–123. ISSN: 0040-5760.
24. Silyakov L., Pesotskaya N.S., Yukhvid V.I. Selfpropagated High-Temperature Synthesis and Properties of Corundum-Based Abrasive Composition Material. Inorg. Mater.,1995, vol. 31, pp. 351-357. ISSN 0020-1685.
25. Tarasov A.G., Gorshkov V.A., Yukhvid V.I. Phase Composition and Microstructure of Al2O3-Cr2O3 Solid Solutions Prepared by Self-Propagating High-Temperature Synthesis. Inorg. Mater., 2007, vol. 43, p. 724. ISSN 0020-1685.
26. Merzhanov A.G., Borovinskaya I.P. Historical Retrospective of SHS: An Autoreview. International. Journal of Self-Propagating High-Temperature Synthesis, 2008, vol. 17, no. 4, pp. 242–265. ISSN 1061-3862. 
27. Romanova R.G., Petrova E.V. Phase Composition of Aluminum–Zirconium Oxide Nanocrystals Prepared by Electrochemical Coprecipitation. Russian Journal of Physical Chemistry, 2006, vol. 80, no. 6, pp. 974–979. ISSN 0036-0244.28.
28. Isasi-Marín J., Pérez-Estébanez M., Díaz-Guerra C., Castillo J.F., Correcher V.,Cuervo-Rodríguez M.R. Structural, magnetic and luminescent characteristics of Pr3+-doped ZrO2 powders synthesized by a sol–gel method. Journal of Physics D: Applied Physics, 2009,vol. 42, no. 7. DOI: 10.1088/0022-3727/42/7/075418.
29. Isasi J., Perez M., Castillo J.F., Correcher V., Aldama I., Arevalo P., Carbajo M.C.Preparation and characterization of Ce0.95Zr0.05O2 nanopowders obtained by sol-gel and template methods. Materials Chemistry and Physics, 2012, vol. 136, no. 1, pp. 160–166. DOI: 10.1016/j.matchemphys.2012.06.046. 
30. Panova T.I., Morozova L.V., Drozdova I.A., Shilova O.A. Sol–Gel Synthesis of Solid Solutions Based on Zirconium and Hafnium Dioxides. Glass Physics and Chemistry, 2011, vol. 37, no. 5, pp. 505–511. ISSN 1087-6596.
31. Kuznetsov P.N., Zhizhaev A.M., Kuznetsova L.I. Mechanochemical Synthesis of Nanosize Metastable Zirconium Oxide. Russian Journal of Applied Chemistry, 2002, vol. 75, no. 2, pp. 171–176. ISSN: 1070-4272.
32. Xu X., Wang X. Fine Tuning of the Sizes and Phases of ZrO2 Nanocrystals. Nano Res., 2009, vol. 2, pp. 891–902. ISSN: 1998-0124.
33. Koroleva L.F. Teoriya i praktika gazovogo analiza [Theory and Practice of Gas Analysis], Ekaterinburg: Ural State Forest Engineering University Publ., 2002, 153 p. (In Russian).
34. Koroleva (Chekhomova) L.F. Synthesis of Spinel-Based Ceramic Pigments from Hydroxycarbonates. Glass Ceram., 2004, vol. 61, no. 9–10, pp. 299–302. ISSN: 0361-7610.
35. Chekhomova L.F., Cherednichenko N.V. Zirconium Phosphate as an Ion-Exchanger for the Separation of Samarium and Neodymium. J. Anal. Chem., 1998, vol. 53, no. 10, pp. 897–901. DOI 1061-9348/98/5310-0897.
36. Gutzov S., Peneva S.K. Formation of the monoclinic zirconia phase by heating from hydrous zirconium oxide. Journal of Materials of Science Letters, 1998, vol. 17, pp. 1535–1537. ISSN: 0261-8028.
37. Toropov N.A., Barzakovskii V.P., Lapin V.V., Kurtseva N.N. Diagrammy sostoyaniya silikatnykh sistem: spravochnik. Vyp. pervyi. Dvoinye sistemy [State Diagrams of Silicate Glasses, Issue 1: Binary Systems]. Leningrad: Nauka,1969, p. 822.(In Russian).
38. Boldyrev V.V. Reaktsionnaya sposobnost tverdykh tel [Reaction Ability of Solids]. Novosibirsk, Sib. Branch RAN, 1997, 303 p. (in Russian).
39. Koroleva L.F. Final Polishing of Metals to Obtain Nanoroughened Surface. Nanotechnologies in Russia, 2012, vol. 7, no. 1–2, pp. 67–75. ISSN 1995-0780
40. Koroleva L.F. Tribochemical Activity of Mixed Oxides of Abrasive Materials in Metal Polishing. Fiz. Khim. Obrab. Mater., 2006, no. 4, pp. 84–92. (In Russian).

           

PDF      

Article reference

Koroleva L. F. Nanoparticulate Zirconia-Modified Solid Solutions of Aluminum-Iron Oxides for Polishing Titanium Metal // Diagnostics, Resource and Mechanics of materials and structures. - 2015. - Iss. 1. - P. 90-102. -
DOI: 10.17804/2410-9908.2015.1.090-102. -
URL: http://eng.dream-journal.org/issues/2015-1/2015-1_10.html
(accessed: 05/25/2024).

 

impact factor
RSCI 0.42

 

MRDMS 2024
Google Scholar


NLR

 

Founder:  Institute of Engineering Science, Russian Academy of Sciences (Ural Branch)
Chief Editor:  S.V. Smirnov
When citing, it is obligatory that you refer to the Journal. Reproduction in electronic or other periodicals without permission of the Editorial Board is prohibited. The materials published in the Journal may be used only for non-profit purposes.
Contacts  
 
Home E-mail 0+
 

ISSN 2410-9908 Registration SMI Эл № ФС77-57355 dated March 24, 2014 © IMACH of RAS (UB) 2014-2024, www.imach.uran.ru